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Evidence of metamorphism at ultrahigh‐pressure (UHP) conditions is documented by the presence of coesite, diamond and/or majoritic garnet. However, the growth of UHP‐stable phases such as majoritic garnet is often volumetrically low, and overprinting during exhumation can obscure evidence of UHP growth, making it difficult to positively identify UHP rocks. In this study, we selected garnet‐kyanite schists from three microdiamond‐bearing localities within the Rhodope Metamorphic Complex, located in eastern Greece. Samples from Xanthi, Sidironero, and Kimi have similar bulk rock compositions, but the pressure–temperature (P–T) paths differ. Because the major phases record vanishingly little evidence of metamorphism at UHP conditions, we analyzed zircon grains with complex textures to evaluate if zircon preserves a record of UHP metamorphism. Zircon grains from all localities have cores and rims separated by a characteristic interface domain, as revealed by cathodoluminescence (CL) imaging. The detrital igneous cores range in age from c. 2.5 Ga to 220 Ma and exhibit a negative Eu* anomaly, a Yb/Gd of 10–100, and variable Th/U (0–1.2). Rims yield dates of 150–125 Ma with Yb/Gd of 0.1–10 and Th/U of 0–0.2. Interface domains yield dates 165–145 Ma with Yb/Gd ranging between 0–1000 and Th/U < 0.2. We interpret the distinctive CL textures and Yb/Gd of the interface domains as evidence of zircon that reacted at UHP. The interface domain in zircon from all petrographic contexts yields variable Yb/Gd ratios that are significantly higher than both cores and rims. We therefore interpret that zircon recrystallized via interface‐coupled dissolution–reprecipitation reaction; this process preferentially partitioned heavy rare earth elements within the interface domain, which explains the higher Yb/Gd ratios. The rim domains equilibrated with the matrix, producing a relatively homogeneous and low Yb/Gd ratio in these domains. The spatial extent and degree of preservation of interface domains are interpreted as a function of the P–T path and minor variations in bulk composition. Interface domains are best preserved in rocks from Xanthi and Sidironero; in these samples, thin, homogeneous, garnet‐stable rims only partially overprint and crosscut the interface domain. In contrast, rocks from Kimi followed a higher‐temperature trajectory and the zircon grains grew large rim domains that overprinted much of the interface domain and the detrital core. Zircon grains from plagioclase‐rich versus quartz‐rich domains within samples from Sidironero show differences in texture, which indicates that local bulk composition can affect what evidence of UHP metamorphism is preserved. Collectively, these samples provide a new, durable marker of metamorphism in UHP rocks and yield new insight about which factors affect the preservation of UHP textures. 

Knobby starfish construct a skeleton with a periodic porous lattice from single-crystal calcite for enhanced protection. 

Abstract To evaluate the mechanisms driving nanoscale trace element mobility in radiation-damaged zircon, we analyzed two well-characterized Archean zircons from the Kaapvaal Craton (southern Africa): one zircon remained untreated and the other was experimentally heated in the laboratory at 1450 °C for 24 h. Atom probe tomography (APT) of the untreated zircon reveals homogeneously distributed trace elements. In contrast, APT of the experimentally heated zircon shows that Y, Mg, Al, and Pb+Yb segregate to a set of two morphologically and crystallographically distinct cluster populations that range from 5 nm tori to 25 nm toroidal polyhedra, which are confirmed to be dislocation loops by transmission electron microscopy (TEM). The dislocation loops lie in {100} and {001} planes; the edges are aligned with <100>, <101>, and <001>. The largest loops (up to 25 nm diameter) are located in {100} and characterized by high concentrations of Mg and Al, which are aligned with <001>. The 207Pb/206Pb measured from Pb atoms located within all of the loops (0.264 ± 0.025; 1σ) is consistent with present-day segregation and confirms that the dislocation loops formed during our experimental treatment. These experimentally induced loops are similar to clusters observed in zircon affected by natural geologic processes. We interpret that differences in cluster distribution, density, and composition between experimentally heated and geologically affected zircon are a function of the radiation dose, the pressure-temperature-time history, and the original composition of the zircon. These findings provide a framework for interpreting the significance of clustered trace elements and their isotopic characteristics in zircon. Our findings also suggest that the processes driving cluster formation in zircon can be replicated under laboratory conditions over human timescales, which may have practical implications for the mineralogical entrapment of significant nuclear elements. 

Abstract Gneiss domes are an integral element of many orogenic belts and commonly provide tectonic windows into deep crustal levels. Gneiss domes in the New England segment of the Appalachian orogen have been classically associated with diapirism and fold interference, but alternative models involving ductile flow have been proposed. We evaluate these models in the Gneiss Dome belt of western New England with U‐Th‐Pb monazite, xenotime, zircon, and titanite petrochronology and major and trace element thermobarometry. These data constrain distinct pressure–temperature–time (P‐T‐t) paths for each unit in the gneiss dome belt tectono‐stratigraphy. The structurally lowest units, Laurentia‐derived migmatitic gneisses of the Waterbury dome, document two stages of metamorphism (455–435 and 400–370 Ma) with peak Acadian metamorphic conditions of ~1.0–1.2 GPa at 750–780°C at 391 ± 7 to 386 ± 4 Ma. The next structurally higher unit, the Gondwana‐derived Taine Mountain Formation, records Taconic (peak conditions: 0.6 GPa, 600°C at 441 ± 4 Ma) and Acadian (peak: 0.8–1.0 GPa, 650°C at 377 ± 4 Ma) metamorphism. The overlying Collinsville Formation yielded a 473 ± 5 Ma crystallization age and evidence for metamorphic conditions of 650°C at 436 ± 4 Ma and 1.2–1.0 GPa, 750–775°C at 397 ± 4 to 385 ± 6 Ma. The structurally higher Sweetheart Mountain Member of the Collinsville Formation yielded only Acadian zircon, monazite, and xenotime dates and evidence for high‐pressure granulite facies metamorphism (1.8 GPa, 815°C) at circa 380–375 Ma. Cover rocks of the dome‐mantling The Straits Schist records peak conditions of ~1 GPa, 700°C at 386 ± 6 to 380 ± 4 Ma. Garnet breakdown to monazite and/or xenotime occurred in all units at circa 375–360 and 345–330 Ma. Peak Acadian metamorphic pressures increase systematically from the structurally lowest to highest units (from 1.0 to 1.8 GPa). This inverted metamorphic sequence is incompatible with the diapiric and fold interference models, which predict the highest pressures at the structurally lowest levels. Based upon P‐T‐t and structural data, we prefer a model involving, first, circa 380 Ma thrust stacking followed by syn‐collisional orogen parallel extension, ductile flow, and rise of the domes between 380 and 365 Ma. Garnet breakdown at circa 345–330 Ma is interpreted to reflect further exhumation during collapse of the Acadian orogenic plateau. These results highlight the power of integrating petrologic constraints with paired geochemical and geochronologic data from multiple chronometers to test structural and tectonic models and show that syn‐convergent orogen parallel ductile flow dramatically modified earlier accretion‐related structures in New England. Further, the Gneiss Dome belt documents gneiss dome development in a syn‐collisional, thick crust setting, providing an ancient example of middle to lower crustal processes that may be occurring today in the modern Himalaya and Pamir Range. 

Abstract Cathodoluminescence (CL) images of kyanite reveal several internal textures, including sector zoning, oscillatory zoning, and cross‐cutting relationships among different domains. Many textures observed in kyanite correspond to discrete events, thereby connecting kyanite textures to the pressure–temperature (P–T) history of the rock. To evaluate the record of metamorphism preserved by kyanite, metapelites were selected from three different orogens that reflectP–Tconditions ranging from amphibolite to ultrahigh‐pressure (UHP) facies. Cross‐correlation of variations in CL intensity, chemistry, and crystal orientation within kyanite indicate the following findings. First, the preservation of original growth zones in kyanite from poly‐metamorphic rocks demonstrates that growth zoning in kyanite persists through metamorphic events and is not erased by diffusion or complete recrystallization. In some samples, kyanite retains evidence of its reaction history during growth. Second, measured changes in absolute crystallographic orientation do not correspond with changes in CL intensity in any of the measured samples, including kyanite twins. Third, both kink banding and undulatory extinction are present across all samples, consistent with rotation about <010> in the (100)[001] slip system. Kyanite from (U)HP samples exhibits higher amplitude undulations than kyanite from lower‐grade lithologies, suggesting that crystallographic orientation data may provide complementary insight about deformation along theP–Tpath. Fourth, specific CL and trace element signatures in kyanite can be correlated with discrete metamorphic histories; yet, CL intensity and colour are affected by multiple elements, not a single controlling element. In sum, multiple generations of kyanite can be identified by careful cross‐correlation of CL and geochemical data, and when combined with crystal orientation data, kyanite provides a robust record of a rock'sP–Tevolution.